Yes, I remember paying for an email account that was POP3 based and part of my ISP monthly fee. I couldn't (easily) access it when away from my home machine because there was no web interface and most importantly - if I changed ISPs, I lost access to my old email address. It's easy for us to forget that permanent email addresses used to be prestige things.
Hotmail with its simple tag line - get hotmail, free web based email was a pioneer.
For me, it was my very first personal cloud based service. At a time when those who had email accounts had them through thick clients like Eudora. It was a big deal. I still retain my hotmail account for sentimental reasons.
To redeem money in Paypal, you needed an account.
If you got an email from a HoTMaiL user, there was a viral auto inserted footer.
And, most important, for these two products, they didn't attempt to track your every click, plain web urls...