I have jj mapped to exit from insert mode and save the file. This trick was found in a long SO thread, plus I never had the need to type something with a double j ;)
I don't even think about it, but apparent pivot on my wrist to hit the 'Esc' key (top left of my keyboard) with my middle finger, rather than my pinkie as would be prescribed by a strict "home row" typing style.
I find emacs's ctrl-meta-foo-bang key combinations to be far more stressful (you have to hit multiple keys in one swell foop) than vi/vim's modal just-one-key-at-a-time standard keystrokes.
Control-[ is the best way to move into command mode. It fits the vi philosophy better than ESC. When hitting ESC you have to lift your hand off the home row. After years of using vim, using ESC feels as inefficient as using arrow keys instead of hjkl.