The point that JWZ is making is that you are by no means guaranteed getting rich, or anywhere close to getting rich by following the "work your ass off as a startup employee" advice that Arrington seems to be providing. It is a pretty sure-fire way to generation substantial ROI for VCs, but it's not a good strategy for coders. Indeed, overall it is probably a less worthwhile strategy than punching a clock to the barest minimum of requirements to earn a salary and then using the remaining free time to acquire new skills (technical or otherwise) or work on personal projects (like one's own startups).
Let's consider two situations:
1) You work X hours, paid Y dollars for that
2) You work 2 * X hours, paid 100 * Y dollars for that, and some VC is paid 1000 * Y dollars.
Should you chose the first?