But when you use a process, you get tons of things for free, the subtask is invoked in parallel, you get isolation and you can control execution for free. Unless you are already writing a multithreaded program or already accept passing objects in memory, using a process is actually easier to write than using a library.
If I use a library, I also need to start using threads and need to invent some core synchronization mechanism. I essentially are reinventing a small scheduler, when I already get this from the OS for free. Also know any crash in the third-party code will crash the whole program, the third-party code has access to the whole address space. With invoking a process you also have a standardized API implemented by the OS.
I'm not sure what you mean by inventing a sync mechanism, all languages come with one. Same with a scheduler, either your language runtime or the OS (or both) will deal with scheduling.
If I use a library, I also need to start using threads and need to invent some core synchronization mechanism. I essentially are reinventing a small scheduler, when I already get this from the OS for free. Also know any crash in the third-party code will crash the whole program, the third-party code has access to the whole address space. With invoking a process you also have a standardized API implemented by the OS.